This is a complicated question without a clear answer, because it depends on:
- The genetics of the Individual
Astringency is a trigeminal sensation, which means it is perceived through a different nerve pathway from olfaction (aroma), gustation (flavor), and somatosensory attributes (heat, cold, pressure, etc); which creates three complications:
1) the source of the sensation (tannins, caffeine, etc)
2) the cross modality of sensation
3) the individual
Starting from the top, 1) a stimuli is not limited to a single response, and thus a compound can exhibit more than one flavor attribute (such as bitter and astringency). Certain co-responses are more common than others, leading to a perceptual effect called adaptation - a learned response to a stimuli (for example: in the USA, cinnamon is predominately paired with sweet things, and thus the presence of cinnamon creates the perception of sweetness even when no sweet compounds are present for a high proportion of the population).
2) While in theory an independent signal could be carried along a nerve pathway, in practice these nerve and neural pathways are
not independent - they interact with each other in various ways. This is called the
cross modality of perception, and it is
far more extensive than most people understand. For example, did you know that loud music in a bar makes you prefer stronger flavors, even if you don't prefer those specific flavors? (which means its a general effect). Or for example, that high pitch sounds in the environment increase the perception of sweet aromas? This level of interaction happens between different perceptions (sight, sound, olfaction, etc) and also happens within a sensation - so the presence of astringency, can, in certain circumstances, increase the perception of other unrelated flavors (such as bitterness).
Finally, 3) all of the above is predicated on the genetics of the individual, which controls the perceptual phenotype of the individual. While some individuals might perceive some compounds as astringent - others won't.
Thus, in conclusion: astringency and bitterness are different sensations that follow different nerve and neural pathway. Astringency and bitterness are common co-responses to the same stimuli, more often found together than apart, leading to adaptation such that the presence of one increase the perception of the other even when its not there. Astringency, which follows the trigeminal nerve is one of the least genetically diverse sensations; bitterness which follows multiple nerves is
the single most genetically diverse perception.
Source: I do this professionally to develop better tasting products.